PVC Degradation and Stabilization Third Edition by George Wypych ISBN 1895198852 9781895198850
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Product details:
ISBN 10: 1895198852
ISBN 13: 9781895198850
Author: George Wypych
PVC stabilization, the most important aspect of formulation and performance of this polymer, is discussed in details. This book contains all information required to design successful stabilization formula for any product made out of PVC.
Separate chapters review information on chemical structure, PVC manufacturing technology, morphology, degradation by thermal energy, UV, gamma, other forms of radiation, mechanodegradation, and chemical degradation. The chapter on analytical methods used in studying of degradative and stabilization processes helps in establishing system of checking results of stabilization with different stabilizing systems. Stabilization and stabilizers are discussed in full detail in the most important chapter of this book. The final chapter contains information on the effects of PVC and its additives on health, safety and environment.
This book contains analysis of all essential papers and patents published until recently on the above subject. It either locates the answers to relevant questions and offers solutions or gives references in which such answers can be found.
PVC Degradation and Stabilization is must to have for chemists, engineers, scientists, university teachers and students, designers, material scientists, environmental chemists, and lawyers who work with polyvinyl chloride and its additives or have any interest in these products. This book is the one authoritative source on the subject.
Table of contents:
Chapter 1: Chemical Structure of PVC
1.1 Repeat Structures and Their Basic Organic Chemistry
1.2 Molecular Weight and Its Distribution
1.3 Prediction of Formation of Irregular Segments
1.4 Irregular Segments
Chapter 2: PVC Manufacture Technology
2.1 Monomer
2.2 Basic Steps of Radical Polymerization
2.3 Polymerization Technology
2.4 Polymerization Conditions and PVC Properties
2.5 Optimal Operation of Industrial PVC Dryer
Chapter 3: PVC Morphology
3.1 Molecular Weight of Polymer (Chain Length)
3.2 Configuration and Conformation
3.3 Chain Folds
3.4 Chain Thickness
3.5 Entanglements
3.6 Crystalline Structure
3.7 Grain Morphology
Chapter 4: Principles of Thermal Degradation
4.1 The Reasons for Polymer Instability
4.2 Mechanisms of Thermal Degradation
4.3 Kinetics
4.4 Results of Thermal Degradation
4.5 Effect of Additives
Chapter 5: Principles of UV Degradation
5.1 Reasons for Polymer Instability – Grotthus-Draper Principle
5.2 Mechanisms of Degradation
5.3 Kinetics
5.4 Results of UV Degradation
5.5 Effect of Additives
Chapter 6: Principles of Degradation by γ-Radiation
6.1 The Reasons for Polymer Instability
6.2 Mechanisms
6.3 Kinetics
6.4 Results
6.5 Effect of Additives
Chapter 7: Degradation by Other Forms of Radiation
7.1 Argon Plasma
7.2 β-Radiation (Electron Beam)
7.3 Corona Discharge
7.4 Ion (Proton) Beam
7.5 Laser
7.6 Metallization
7.7 Microwave
7.8 Neutron Irradiation
7.9 Oxygen Plasma
7.10 X-Rays
7.11 Ultrasonic
Chapter 8: Mechanodegradation
Chapter 9: Chemical Degradation
9.1 Methods of Chemical Dehydrochlorination
9.2 Kinetics and Mechanisms of Reaction
Chapter 10: Analytical Methods
10.1 Heat Stability Test
10.2 Thermogravimetric Analysis
10.3 Combustion
10.4 Optical Properties
10.5 Spectroscopic Methods
10.6 Chromatographic Methods
10.7 Mechanical Properties
10.8 Other Essential Methods of Testing
10.9 International Standards
Chapter 11: Principles of Stabilization
11.1 Functions of PVC Stabilizers
11.2 Theories
11.3 Stabilizer Groups
Chapter 12: Health & Safety and Environmental Impact
12.1 Toxic Substance Control
12.2 Carcinogenic Effect
12.3 Teratogenic and Mutagenic Effect
12.4 Allergy
12.5 Workplace Exposure Limits
12.6 Exposure from Consumer Products
12.7 Drinking Water
12.8 Food Regulatory Acts
12.9 Toxicity of Stabilizers
12.10 Lifecycle Assessment
12.11 Reformulation in Waste Processing
12.12 Photodegradable PVC
12.13 Energy Recovery
12.14 Waste Processing
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Tags: George Wypych, PVC, Degradation, Stabilization