Alkynes in Cycloadditions 1st Edition by Maretina I Alexandrovna, Boris I Ionin, John C Tebby ISBN 1118709314 9781118709313

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Product details:

ISBN 10: 1118709314

ISBN 13: 9781118709313 

Author: Maretina I. Alexandrovna, Boris I. Ionin, John C. Tebby

Acetylene systems present a new route to cyclic compounds as an alternative to more traditional methods employed in classical organic chemistry. The synthesis of cyclic structures based on acetylene systems has important applications in the formation of nanostructures, naturally occurring compounds and chemosensory materials for the design of nonlinear optics, electronic and photonic devices.

Alkynes in Cycloadditions presents a modern review of regioselective synthesis of aromatic and non-aromatic carbocyclic and heterocyclic ring systems based primarily on [2+2+2] and [4+2] cycloadditions, and other reactions of acetylenic units including enediynes and enyne-allenes.

Topics covered include:

• New strategies for the formation of aromatic and polynuclear hydrocarbons based on (Z)-hex-3-en-1,5-diyne and (Z)-hepta-1,2,4-triene-6-yne blocks.
• One-step synthesis of benzene derivatives, β-substituted naphthalenes and acenes by the cycloaromatization of enediynes and enyne-allenes by Bergman, Myers-Saito and Shmittel.
• Mechanisms of cycloaromatization resulting in the formation of fulvene and indene systems.
• Heterocyclization involving enyne-carbodiimides.
• New achievements in classical cycloaddition reactions such as the Diels-Alder condensation with acetylenic dienophiles and [2+2] cycloadditions with acetylene components

Alkynes in Cycloadditions presents a comprehensive summary of the literature on methods for the synthesis of ring systems from acetylenes for academic researchers working in the fields of organic synthesis, physical organic chemistry, organometallic chemistry, catalysis, materials science, nanomaterials and biochemistry.

Table of contents:

Front Matter

Chapter 1: Introduction

Chapter 2: Regioselective Syntheses of Polysubstituted Benzenes Catalyzed by Transition Metal Complexes

Chapter 3: Radical Cycloaromatization of Systems Containing (Z)-3-hexene-1,5-diynes and (Z)-1,2,4-heptatrien-6-ynes and Related Heteroatomic Blocks

Chapter 4: Selected Cycloaddition and Heterocyclization Reactions with Unusual Acetylenic and Allenic Starting Compounds

Chapter 5: Concluding Remarks

References

Index

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Tags: Maretina I Alexandrovna, Boris I Ionin, John C Tebby, Alkynes, Cycloadditions