Chemical kinetics from molecular structure to chemical reactivity 1st Edition by Luis G Arnaut, Sebastiao J Formosinho, Hugh Burrows ISBN 0444521860 9780080469348

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Product details:

ISBN 10: 0444521860 

ISBN 13: 9780080469348

Author: Luís G. Arnaut, Sebastião J. Formosinho, Hugh Burrows

Chemical Kinetics bridges the gap between beginner and specialist with a path that leads the reader from the phenomenological approach to the rates of chemical reactions to the state-of-the-art calculation of the rate constants of the most prevalent reactions: atom transfers, catalysis, proton transfers, substitution reactions, energy transfers and electron transfers. For the beginner provides the basics: the simplest concepts, the fundamental experiments, and the underlying theories. For the specialist shows where sophisticated experimental and theoretical methods combine to offer a panorama of time-dependent molecular phenomena connected by a new rational. Chemical Kinetics goes far beyond the qualitative description: with the guidance of theory, the path becomes a reaction path that can actually be inspected and calculated. But Chemical Kinetics is more about structure and reactivity than numbers and calculations. A great emphasis in the clarity of the concepts is achieved by illustrating all the theories and mechanisms with recent examples, some of them described with sufficient detail and simplicity to be used in general chemistry and lab courses.

Table of contents:

1. Introduction

2. Reaction rate laws

3. Experimental methods

4. Rate constants and reaction orders

5. Collisions and molecular dynamics

6. Reactivity in thermalized systems

7. Structure-Reactivity Relationships

8. Unimolecular Reactions

9. Reaction in solution

10. Reactions in surfaces

11. Nucleophilic substitution reactions

12. Chain reactions

13. Acid-base catalysis and proton-transfer reactions

14. Enzyme catalysis

15. Transitions between electronic states

16. Electron transfers

17. Fractals, chaos and oscillatory reactions

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Tags: Luis G Arnaut, Sebastiao J Formosinho, Hugh Burrows, Chemical Kinetics, Molecular Structure, Chemical Reactivity