Concepts and Terminology in Organic Stereochemistry 1st edition by Kaloustian – Ebook PDF Instant Download/Delivery: 9780080472317, 0080472311
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• ISBN 10:0080472311
• ISBN 13: 9780080472317
• Author:Mose K. Kaloustian
Concepts and Terminology in Organic Stereochemistry
In the last quarter century there have been only two seminal contributions in the field of organic stereochemistry – both by Kurt Mislow and his coworkers – ones that have clarified the basic concepts of stereotopicity and chirotopicity. Not withstanding a few other sporadic contributions by others, to date there have been no systematic attempts to unify and develop the conceptual framework and terminology of organic stereochemistry. Existing terms are frequently misused or abused, needed terms – redundant, confusing or controversial – are invented randomly, and yet other needed terms have not seen the light of day.
This three-part work presents the elements of a simple, uniform and comprehensive language of the stereochemical underpinnings of organic chemistry. It is essential reading for industrial chemists, graduate students, university professors and industrial researchers in the field of Organic Stereochemistry.
* Presents the elements of a simple, uniform and comprehensive language of organic stereochemistry.
* Unifies and develops a comprehensive language of organic stereochemistry
* Presents concepts and classifications which are universal.
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Additional ISBNs
9780080962443
Subjects
Science,
Chemistry
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Concepts and Terminology in Organic Stereochemistry 1st Table of contents:
Front Cover
The Classification of Morphic Relationships, Morphizations, Topic Relationships, and Topizations
Copyright Page
Contents of Volume 1
Chapter 1. On the Geometric Basis of Metric Relationships and Metrization Processes of Carbogenic Mo
I. Metric Relationships of Geometric Figures
II. Geometricity – Classification of Metric Relationships of Geometric Figures. HEDAN Classificati
III. Geometrization – Classification of Metrizations of Geometric Figures. HEDAN Classification
Chapter 2. Systematic Classification of Morphic (& “Meric”) Relationships and Morphizations (& “Meri
I. Morphic Relationships
II. Morphizations
Chapter 3. On the Geometric Basis of Topic Relationships and Topization Processes of Carbogenic Mole
I. Geotopicity – Classification of Topic Relationships in Geometric Figures. hedan Classification
II. Geotopizations – Classification of Topizations in Geometric Figures. hedan Classification
Chapter 4. Systematic Classification of Topic Relationships and Topization Processes in Carbogenic M
I. Topic Relationships
II. Geotopizations
Chapter 5. Correlations of Morphic with Topic Relationships, and, Morphizations with Topizations in
I. Correlation of (Geo)Metric Relationships with (Geo)Topic Relationships (HEDAN vs. hedan)
II. Correlation of Morphic Relationships with Topic Relationships (HEDAN vs. hedan)
III. Correlation of (Geo)Metrizations with (Geo)Topizations (HEDAN vs. hedan)
IV. Correlation of Morphizations with Topizations (HEDAN vs. hedan)
Chapter 6. Geometric Segmentation of Carbogenic Molecules. Geometric Origin of Molecular Stereogenic
I. Geometric Simplexes (Geoplexes) and Multiplexes (Multigeoplexes) – Astereogeoplexes and Stereogeo
II. Coplanarly-and/or Perpendicularly-linked Multiplexes
III. Geostereogens (Geometric Stereogenic Multiplexes) and Geoastereogens (Geometric Astereogenic Mu
IV. Stereogenicity vs. Chirality of Multiplexes
V. Applications to Carbogenic Systems
VI. Stereogenicity vs. Chirality of Molecules/Molecular Species
VII Stereogenicity of Polymultiplexes
Chapter 7. Geometric Segmentation of Carbogenic Molecules. Geometric Origin of Molecular Stereogenic
I. Angularly-Linked Multiplexes
II. Geostereogens (Geometric Stereogenic Multiplexes) and Geoastereogens (Geometric Astereogenic Mul
III. Stereogenicity vs. Chirality of Angular Multiplexes
IV. Applications to Carbogenic Systems
Addendum A. Specifying Compositions of Two-, Three- and Four-Component Mixtures
A1. Determination of ee, de, ae, and ne from Known Compositions
A2. Determination of Compositions from ee, de, ae, and ne
A3. Relationship of S2/S1 and ∆∆G*
Addendum B. Defining the ∆pS Scale
References & Notes
Index
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