Copper Mediated Cross Coupling Reactions 1st Edition by Gwilherm Evano, Nicolas Blanchard ISBN 1118690680 9781118690680

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Product details:

ISBN 10: 1118690680

ISBN 13: 9781118690680

Author:  Gwilherm Evano, Nicolas Blanchard 

Copper-Mediated Cross-Coupling Reactions 1st Edition: Providing comprehensive insight into the use of copper in cross-coupling reactions, Copper-Mediated Cross-Coupling Reactions provides a complete up-to-date collection of the available reactions and catalytic systems for the formation of carbon-heteroatom and carbon-carbon bonds. This essential reference covers a broad scope of copper-mediated reactions, their variations, key advances, improvements, and an array of academic and industrial applications that have revolutionized the field of organic synthesis. The text also discusses the mechanism of these transformations, the use of copper as cost-efficient alternative to palladium, as well as recently developed methods for conducting copper-mediated reactions with supported catalysts.

 

Copper-Mediated Cross-Coupling Reactions 1st Edition Table of contents:

Part I: Formation of C–heteroatom bonds

• Modern Ullmann–Goldberg chemistry: arylation of N-nucleophiles with aryl halides
• Ullmann condensation today: arylation of alcohols and thiols with aryl halides
• Copper-catalyzed formation of C–P bonds with aryl halides
• Alternative and emerging reagents for the arylation of heteronucleophiles
• Beyond Ullmann–Goldberg chemistry: vinylation, alkynylation, and allenylation of heteronucleophiles
• Aromatic/vinylic Finkelstein reaction
• Insights into the mechanism of modern Ullmann–Goldberg coupling reactions

Part II: Formation of C–C bonds

• Modern copper-catalyzed Hurtley reaction: efficient C-arylation of CH-acid derivatives
• Copper-catalyzed cyanations of aryl halides and related compounds
• Copper-mediated aryl–aryl bond formation leading to biaryls: a century after the Ullmann breakthrough
• Copper-catalyzed alkynylation, alkenylation, and allylation reactions of aryl derivatives

 

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