Handbook of Organopalladium Chemistry for Organic Synthesis 1st Edition by Ei Ichi Negishi, Armin de Meijere ISBN 0471315060 978-0471315063

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Product details:

ISBN 10: 0471315060

ISBN 13: 978-0471315063 

Author: Ei-ichi Negishi, Armin de Meijere

Organized to provide maximum utility to the bench synthetic chemist.* The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry.* Contributors include over 24 world authorities in the field.

Table of contents:

PART I. Background and Fundamental Concepts

1. Historical Background of Organopalladium Chemistry

2. Fundamental Properties of Palladium and Patterns of the Reactions of Palladium and Its Complexes

3. Background for Part II

PART II. Palladium Complexes and Organopalladium Compounds

1. Metallic Palladium and Simple Palladium Compounds

2. Halide and Oxide Complexes of Palladium

3. Phosphine, Phosphite, and Arsine Complexes of Palladium

4. Complexes of Palladium with Sulfur- and Selenium-Containing Ligands

5. π-Complexes of Palladium with Olefins and Alkynes

6. Complexes of Palladium with Nitrogen-Containing Ligands

7. Complexes of Palladium with Carbon Monoxide

8. Chiral Palladium Complexes and Chiral Ligands

9. High-Valent Palladium Complexes

10. Organopalladium Compounds: General Considerations

11. Methods for the Preparation of Organopalladium Compounds

PART III. Palladium-Catalyzed Cross-Coupling Reactions

1. General Principles of Cross-Coupling Reactions

2. Coupling of Organomagnesium, Organolithium, and Related Reagents

3. Coupling of Organozinc Reagents (Negishi Coupling)

4. Coupling of Organoboron Reagents (Suzuki Coupling)

5. Coupling of Organostannanes (Stille Coupling)

6. Coupling of Organosilanes (Hiyama Coupling)

7. Coupling of Organogermanes and Organolead Compounds

8. Coupling of Alkynes (Sonogashira Reaction)

9. Coupling of Organocopper and Organosilver Compounds

10. Coupling of Organoaluminum and Organobismuth Compounds

11. Asymmetric Cross-Coupling Reactions

12. Applications of Cross-Coupling Reactions in Organic Synthesis

PART IV. Carbopalladation and Heck-Type Reactions

1. General Overview of Carbopalladation

2. Intermolecular Heck Reactions

3. Intramolecular Heck Reactions and Cyclization Processes

4. Tandem and Cascade Carbopalladation Reactions

5. Carbopalladation in Polymer Chemistry

6. Related Reactions Involving Carbopalladation Pathways

PART V. π-Allyl and Related Palladium Chemistry

1. π-Allylpalladium Complexes: Formation and Structure

2. Nucleophilic Substitution Reactions of π-Allylpalladium Complexes

3. Reactions with Oxygen and Nitrogen Nucleophiles

4. Reactions with Carbon Nucleophiles

5. Asymmetric π-Allylpalladium Reactions

6. π-Benzyl, π-Crotyl, and Related Complexes

7. Applications in Natural Product Synthesis

PART VI. Carbonylation and Acylpalladium Chemistry

1. Formation and Reactions of Acylpalladium Complexes

2. Palladium-Catalyzed Carbonylation Reactions

3. Hydrocarboxylation, Hydroesterification, and Related Processes

4. Lactonization, Lactamization, and Amide Formation

5. Migratory Insertion and CO Incorporation Reactions

6. Applications in Polymer and Material Synthesis

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