Modern Fluoroorganic Chemistry Synthesis Reactivity Applications 2nd Edition by Peer Kirsch ISBN 3527331662 9783527331666

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Product details:

ISBN 10: 3527331662

ISBN 13: 978-3527331666

Author:  Peer Kirsch 

Modern Fluoroorganic Chemistry: Synthesis, Reactivity, Applications 2nd Edition: The second edition of this classic reference work has been completely revised and updated, as well as being enlarged by 20% to reflect the latest developments in synthetic organic fluorine chemistry, taking into account new applications in materials science and medicinal chemistry.

The new developments in transition-metal-catalyzed methods for the introduction of fluorine and fluorinated groups are discussed. In addition, new chapters have been added on such important applications as organic electronics (OLEDs) and fluorinated dyes. Appendices containing synthetic procedures and conversions round off this comprehensive work.

This work is a valuable reference for fluorine chemists that also provides nonspecialists with an introduction to the field.

From reviews of the first edition:
”… a well-produced book with attractive graphics, photos and schemes. Throughout the book, coloured electrostatic maps of small
organofluorine compounds are used toillustrate charge distributions. These are effective as well as attractive. I would point any organic chemist to this book who wants to learn about and do some fluorine chemistry. It provides uncluttered descriptions and a clear orientation to the literature in this important area of the organic chemistry.”

CHEMBIOCHEM – A European Journal of Chemical Biology

 

Modern Fluoroorganic Chemistry: Synthesis, Reactivity, Applications 2nd Edition Table of contents:

• Part I: Synthesis of Complex Organofluorine Compounds

  • Introduction of Fluorine

    • Perfluorination and Selective Direct Fluorination
    • Electrochemical Fluorination (ECF)
    • Nucleophilic Fluorination
    • Synthesis and Reactivity of Fluoroaromatic Compounds
    • Transformations of Functional Groups
    • “Electrophilic” Fluorination

  • Perfluoroalkylation

    • Radical Perfluoroalkylation
    • Nucleophilic Perfluoroalkylation
    • “Electrophilic” Perfluoroalkylation
    • Difluorocarbene and Fluorinated Cyclopropanes

  • Selected Fluorinated Structures and Reaction Types

    • Difluoromethylation and Halodifluoromethylation
    • The Perfluoroalkoxy Group
    • The Perfluoroalkylthio Group and Sulfur-Based Super-Electron-Withdrawing Groups
    • The Pentafluorosulfanyl Group and Related Structures

  • The Chemistry of Highly Fluorinated Olefins

    • Fluorinated Polymethines
    • Fluorinated Enol Ethers as Synthetic Building Blocks

• Part II: Fluorous Chemistry

  • Fluorous Chemistry

    • Fluorous Biphase Catalysis

  • Fluorous Synthesis and Combinatorial Chemistry

    • Fluorous Synthesis
    • Separation on Fluorous Stationary Phases
    • Fluorous Concepts in Combinatorial Chemistry

• Part III: Applications of Organofluorine Compounds

  • Halofluorocarbons, Hydrofluorocarbons, and Related Compounds

    • Polymers and Lubricants
    • Applications in the Electronics Industry
    • Fluorinated Dyes
    • Liquid Crystals for Active Matrix Liquid Crystal Displays
    • Fluorine in Organic Electronics

  • Pharmaceuticals and Other Biomedical Applications

    • Why Fluorinated Pharmaceuticals?
    • Lipophilicity and Substituent Effects
    • Hydrogen Bonding and Electrostatic Interactions
    • Stereoelectronic Effects and Conformation
    • Metabolic Stabilization and Modulation of Reaction Centers
    • Bioisosteric Mimicking
    • Mechanism-Based “Suicide” Inhibition
    • Fluorinated Radiopharmaceuticals
    • Inhalation Anesthetics
    • Blood Substitutes and Respiratory Fluids
    • Contrast Media and Medical Diagnostics
    • Agricultural Chemistry

 

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